The boats sail about twenty miles up the Missouri stopping southeast of present Vermillion, South Dakota. While investigating some minerals, Lewis is overcome by caustic fumes. Pvt. Gass is elected to the rank of sergeant replacing Charles Floyd who recently died.
Caustic Fumes
Capt lewis was near being Poisened by the Smell in pounding this Substance I belv to be arsenic or Cabalt. [He] took a Dost of Salts this evening to carry of the effects of (arsenec) or cobalt which he was trying to find out the real quallity
—William Clark
Mineral Specimens
This Bluff contain Pyrites alum, Copperass & a Kind Markesites . . . . arsenic or Cabalt . . . . Cops. ans [copperas] and almin [alum] pure & Straters of white & brown earth of 6 Inch. thick.
—William Clark